by Simonelli, L., Saini, N. L., Sala, M. Moretti, Mizuguchi, Y., Takano, Y., Takeya, H., Mizokawa, T. and Monaco, G.
Abstract:
We have studied electronic and magnetic properties of the K0.8Fe1.6Se2 superconductor by x-ray absorption and emission spectroscopy. Detailed temperature-dependent measurements along with a direct comparison with the binary FeSe system have revealed coexisting electronic phases: a majority phase with a high-spin Fe3+ state and a minority phase with an intermediate-spin Fe2+ state. The effect of high-temperature annealing suggests that the compressed phase with a lower-spin Fe2+ state is directly related to the high-T-c superconductivity in the title system. The results clearly underline the glassy nature of superconductivity in the electronically inhomogeneous K0.8Fe1.6Se2, similar to the superconductivity in granular phases.
Reference:
Coexistence of different electronic phases in the K0.8Fe1.6Se2 superconductor: A bulk-sensitive hard x-ray spectroscopy study (Simonelli, L., Saini, N. L., Sala, M. Moretti, Mizuguchi, Y., Takano, Y., Takeya, H., Mizokawa, T. and Monaco, G.), In PHYSICAL REVIEW B, AMER PHYSICAL SOC, volume 85, 2012.
Bibtex Entry:
@article{ ISI:000304932200008,
Author = {Simonelli, L. and Saini, N. L. and Sala, M. Moretti and Mizuguchi, Y.
   and Takano, Y. and Takeya, H. and Mizokawa, T. and Monaco, G.},
Title = {{Coexistence of different electronic phases in the K0.8Fe1.6Se2
   superconductor: A bulk-sensitive hard x-ray spectroscopy study}},
Journal = {{PHYSICAL REVIEW B}},
Year = {{2012}},
Volume = {{85}},
Number = {{22}},
Month = {{JUN 7}},
Abstract = {{We have studied electronic and magnetic properties of the K0.8Fe1.6Se2
   superconductor by x-ray absorption and emission spectroscopy. Detailed
   temperature-dependent measurements along with a direct comparison with
   the binary FeSe system have revealed coexisting electronic phases: a
   majority phase with a high-spin Fe3+ state and a minority phase with an
   intermediate-spin Fe2+ state. The effect of high-temperature annealing
   suggests that the compressed phase with a lower-spin Fe2+ state is
   directly related to the high-T-c superconductivity in the title system.
   The results clearly underline the glassy nature of superconductivity in
   the electronically inhomogeneous K0.8Fe1.6Se2, similar to the
   superconductivity in granular phases.}},
Publisher = {{AMER PHYSICAL SOC}},
Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Simonelli, L (Corresponding Author), European Synchrotron Radiat Facil, Boite Postale 220, F-38043 Grenoble, France.
   Simonelli, L.; Sala, M. Moretti; Monaco, G., European Synchrotron Radiat Facil, F-38043 Grenoble, France.
   Saini, N. L., Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy.
   Mizuguchi, Y.; Takano, Y.; Takeya, H., Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan.
   Mizuguchi, Y.; Takano, Y.; Takeya, H., JST TRIP, Tsukuba, Ibaraki 3050047, Japan.
   Mizokawa, T., Univ Tokyo, Dept Phys, Kashiwa, Chiba 2778561, Japan.
   Mizokawa, T., Univ Tokyo, Dept Complex Sci & Engn, Kashiwa, Chiba 2778561, Japan.}},
DOI = {{10.1103/PhysRevB.85.224510}},
Article-Number = {{224510}},
ISSN = {{1098-0121}},
Keywords-Plus = {{COMPLEXES}},
Research-Areas = {{Materials Science; Physics}},
Web-of-Science-Categories  = {{Materials Science, Multidisciplinary; Physics, Applied; Physics,
   Condensed Matter}},
ResearcherID-Numbers = {{Mizuguchi, Yoshikazu/Q-9979-2017
   Saini, Naurang/J-7918-2013
   Mizokawa, Takashi/E-3302-2015
   Sala, Marco Moretti/H-1034-2014
   Moretti, Marco/AAF-9255-2019
   Monaco, Giulio/AAW-4387-2020
   Simonelli, Laura/I-1963-2015
   Takano, Yoshihiko/H-2788-2011}},
ORCID-Numbers = {{Mizuguchi, Yoshikazu/0000-0002-4771-7805
   Saini, Naurang/0000-0003-3684-1517
   Mizokawa, Takashi/0000-0002-7682-2348
   Sala, Marco Moretti/0000-0002-9744-9976
   Moretti, Marco/0000-0002-9744-9976
   Monaco, Giulio/0000-0003-2497-6422
   Takano, Yoshihiko/0000-0002-1541-6928}},
Number-of-Cited-References = {{38}},
Times-Cited = {{24}},
Usage-Count-Last-180-days = {{0}},
Usage-Count-Since-2013 = {{33}},
Journal-ISO = {{Phys. Rev. B}},
Doc-Delivery-Number = {{954FO}},
Unique-ID = {{ISI:000304932200008}},
DA = {{2020-12-22}},
}

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