by Simonelli, L., Saini, N. L., Sala, M. Moretti, Mizuguchi, Y., Takano, Y., Takeya, H., Mizokawa, T. and Monaco, G.
Abstract:
We have studied electronic and magnetic properties of the K0.8Fe1.6Se2 superconductor by x-ray absorption and emission spectroscopy. Detailed temperature-dependent measurements along with a direct comparison with the binary FeSe system have revealed coexisting electronic phases: a majority phase with a high-spin Fe3+ state and a minority phase with an intermediate-spin Fe2+ state. The effect of high-temperature annealing suggests that the compressed phase with a lower-spin Fe2+ state is directly related to the high-T-c superconductivity in the title system. The results clearly underline the glassy nature of superconductivity in the electronically inhomogeneous K0.8Fe1.6Se2, similar to the superconductivity in granular phases.
Reference:
Coexistence of different electronic phases in the K0.8Fe1.6Se2 superconductor: A bulk-sensitive hard x-ray spectroscopy study (Simonelli, L., Saini, N. L., Sala, M. Moretti, Mizuguchi, Y., Takano, Y., Takeya, H., Mizokawa, T. and Monaco, G.), In PHYSICAL REVIEW B, AMER PHYSICAL SOC, volume 85, 2012.
Bibtex Entry:
@article{ ISI:000304932200008, Author = {Simonelli, L. and Saini, N. L. and Sala, M. Moretti and Mizuguchi, Y. and Takano, Y. and Takeya, H. and Mizokawa, T. and Monaco, G.}, Title = {{Coexistence of different electronic phases in the K0.8Fe1.6Se2 superconductor: A bulk-sensitive hard x-ray spectroscopy study}}, Journal = {{PHYSICAL REVIEW B}}, Year = {{2012}}, Volume = {{85}}, Number = {{22}}, Month = {{JUN 7}}, Abstract = {{We have studied electronic and magnetic properties of the K0.8Fe1.6Se2 superconductor by x-ray absorption and emission spectroscopy. Detailed temperature-dependent measurements along with a direct comparison with the binary FeSe system have revealed coexisting electronic phases: a majority phase with a high-spin Fe3+ state and a minority phase with an intermediate-spin Fe2+ state. The effect of high-temperature annealing suggests that the compressed phase with a lower-spin Fe2+ state is directly related to the high-T-c superconductivity in the title system. The results clearly underline the glassy nature of superconductivity in the electronically inhomogeneous K0.8Fe1.6Se2, similar to the superconductivity in granular phases.}}, Publisher = {{AMER PHYSICAL SOC}}, Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}}, Type = {{Article}}, Language = {{English}}, Affiliation = {{Simonelli, L (Corresponding Author), European Synchrotron Radiat Facil, Boite Postale 220, F-38043 Grenoble, France. Simonelli, L.; Sala, M. Moretti; Monaco, G., European Synchrotron Radiat Facil, F-38043 Grenoble, France. Saini, N. L., Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy. Mizuguchi, Y.; Takano, Y.; Takeya, H., Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan. Mizuguchi, Y.; Takano, Y.; Takeya, H., JST TRIP, Tsukuba, Ibaraki 3050047, Japan. Mizokawa, T., Univ Tokyo, Dept Phys, Kashiwa, Chiba 2778561, Japan. Mizokawa, T., Univ Tokyo, Dept Complex Sci & Engn, Kashiwa, Chiba 2778561, Japan.}}, DOI = {{10.1103/PhysRevB.85.224510}}, Article-Number = {{224510}}, ISSN = {{1098-0121}}, Keywords-Plus = {{COMPLEXES}}, Research-Areas = {{Materials Science; Physics}}, Web-of-Science-Categories = {{Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter}}, ResearcherID-Numbers = {{Mizuguchi, Yoshikazu/Q-9979-2017 Saini, Naurang/J-7918-2013 Mizokawa, Takashi/E-3302-2015 Sala, Marco Moretti/H-1034-2014 Moretti, Marco/AAF-9255-2019 Monaco, Giulio/AAW-4387-2020 Simonelli, Laura/I-1963-2015 Takano, Yoshihiko/H-2788-2011}}, ORCID-Numbers = {{Mizuguchi, Yoshikazu/0000-0002-4771-7805 Saini, Naurang/0000-0003-3684-1517 Mizokawa, Takashi/0000-0002-7682-2348 Sala, Marco Moretti/0000-0002-9744-9976 Moretti, Marco/0000-0002-9744-9976 Monaco, Giulio/0000-0003-2497-6422 Takano, Yoshihiko/0000-0002-1541-6928}}, Number-of-Cited-References = {{38}}, Times-Cited = {{24}}, Usage-Count-Last-180-days = {{0}}, Usage-Count-Since-2013 = {{33}}, Journal-ISO = {{Phys. Rev. B}}, Doc-Delivery-Number = {{954FO}}, Unique-ID = {{ISI:000304932200008}}, DA = {{2020-12-22}}, }
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