by Aruta, C., Minola, M., Galdi, A., Ciancio, R., Petrov, A. Yu, Brookes, N. B., Ghiringhelli, G., Maritato, L. and Orgiani, P.
Abstract:
We here report on the occurrence of strong orbital order driven by off-stoichiometry in oxide manganite films. Multiple-electronic-valence Mn ions are possibly substituted into the perovskite atomic A site (namely, A-site manganites). By combining state-of-the-art synchrotron ultrafine spectroscopies, we did provide evidence of a high ferromagnetic metallic state together with a strong orbital order of Mn ions, despite that the kinetic energy of the free charge carriers should prevent long-range orbital order. By varying the total amount of Mn ions at the perovskite A site, a specific orbital order (either in-plane or out-of-plane) can be determined.
Reference:
Off-stoichiometry effect on orbital order in A-site manganites probed by x-ray absorption spectroscopy (Aruta, C., Minola, M., Galdi, A., Ciancio, R., Petrov, A. Yu, Brookes, N. B., Ghiringhelli, G., Maritato, L. and Orgiani, P.), In PHYSICAL REVIEW B, AMER PHYSICAL SOC, volume 86, 2012.
Bibtex Entry:
@article{ ISI:000309176000001,
Author = {Aruta, C. and Minola, M. and Galdi, A. and Ciancio, R. and Petrov, A. Yu
   and Brookes, N. B. and Ghiringhelli, G. and Maritato, L. and Orgiani, P.},
Title = {{Off-stoichiometry effect on orbital order in A-site manganites probed by
   x-ray absorption spectroscopy}},
Journal = {{PHYSICAL REVIEW B}},
Year = {{2012}},
Volume = {{86}},
Number = {{11}},
Month = {{SEP 24}},
Abstract = {{We here report on the occurrence of strong orbital order driven by
   off-stoichiometry in oxide manganite films. Multiple-electronic-valence
   Mn ions are possibly substituted into the perovskite atomic A site
   (namely, A-site manganites). By combining state-of-the-art synchrotron
   ultrafine spectroscopies, we did provide evidence of a high
   ferromagnetic metallic state together with a strong orbital order of Mn
   ions, despite that the kinetic energy of the free charge carriers should
   prevent long-range orbital order. By varying the total amount of Mn ions
   at the perovskite A site, a specific orbital order (either in-plane or
   out-of-plane) can be determined.}},
Publisher = {{AMER PHYSICAL SOC}},
Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Aruta, C (Corresponding Author), Univ Naples Federico II, CNR SPIN, I-80125 Naples, Italy.
   Aruta, C., Univ Naples Federico II, CNR SPIN, I-80125 Naples, Italy.
   Aruta, C., Univ Naples Federico II, Dept Phys Sci, I-80125 Naples, Italy.
   Minola, M., Politecn Milan, CNISM, I-20133 Milan, Italy.
   Minola, M.; Ghiringhelli, G., Politecn Milan, Dept Phys, I-20133 Milan, Italy.
   Galdi, A.; Maritato, L.; Orgiani, P., Univ Salerno, CNR SPIN, I-84084 Fisciano, SA, Italy.
   Galdi, A.; Maritato, L.; Orgiani, P., Univ Naples Federico II, Dept Ind Engn, I-80125 Naples, Italy.
   Ciancio, R.; Petrov, A. Yu, CNR IOM TASC, I-34146 Trieste, Italy.
   Brookes, N. B., European Synchrotron Radiat Facil, F-38043 Grenoble, France.
   Ghiringhelli, G., Politecn Milan, CNR SPIN, I-20133 Milan, Italy.}},
DOI = {{10.1103/PhysRevB.86.115132}},
Article-Number = {{115132}},
ISSN = {{2469-9950}},
EISSN = {{2469-9969}},
Keywords-Plus = {{PHASE-DIAGRAM; TRANSITION; DICHROISM; PHYSICS}},
Research-Areas = {{Materials Science; Physics}},
Web-of-Science-Categories  = {{Materials Science, Multidisciplinary; Physics, Applied; Physics,
   Condensed Matter}},
Author-Email = {{carmela.aruta@spin.cnr.it
   pasquale.orgiani@spin.cnr.it}},
ResearcherID-Numbers = {{Galdi, Alice/J-5072-2012
   Aruta, Carmela/L-2957-2015
   Ciancio, Regina/R-8845-2016
   Brookes, Nicholas B/C-6718-2019
   Orgiani, Pasquale/AAC-8703-2019
   Ghiringhelli, Giacomo/D-1159-2014
   Orgiani, Pasquale/E-7146-2013
   }},
ORCID-Numbers = {{Galdi, Alice/0000-0003-2863-5393
   Aruta, Carmela/0000-0002-6917-6667
   Brookes, Nicholas B/0000-0002-1342-9530
   Orgiani, Pasquale/0000-0002-1082-9651
   Ghiringhelli, Giacomo/0000-0003-0867-7748
   Orgiani, Pasquale/0000-0002-1082-9651
   Minola, Matteo/0000-0003-4084-0664}},
Funding-Acknowledgement = {{Italian MIURMinistry of Education, Universities and Research (MIUR)
   {[}PRIN 20094W2LAY]; European CommunityEuropean Community (EC) {[}212348
   NFFA]; Progetto strategico NFFA(fondi-MIUR)}},
Funding-Text = {{This work was supported by the Italian MIUR Grant No. PRIN 20094W2LAY,
   Ordine orbitale e di spin nelle eterostrutture di cuprati e manganiti.
   R.C.'s research activity has received funding from the European
   Community's Seventh Framework Programme 2007 - 2011 under Grant
   Agreement No. 212348 NFFA and Progetto strategico NFFA(fondi-MIUR
   2012-2013).}},
Number-of-Cited-References = {{43}},
Times-Cited = {{7}},
Usage-Count-Last-180-days = {{2}},
Usage-Count-Since-2013 = {{30}},
Journal-ISO = {{Phys. Rev. B}},
Doc-Delivery-Number = {{011OZ}},
Unique-ID = {{ISI:000309176000001}},
DA = {{2020-12-22}},
}

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