by Annese, E, Rueff, JP, Vanko, G, Grioni, M, Braicovich, L and Degiorgi, L, Gusmeroli, R and Dallera, C
Abstract:
We present spectroscopic data on the electronic structure of YbS under pressure. From resonant x-ray emission and x-ray absorption spectra in the high-resolution partial fluorescence yield mode, we find that the Yb valence increases from 2.3 at ambient pressure to 2.6 at 360 kbar. The accuracy of these estimates is enhanced by a combined analysis of emission spectra measured as a function of the incident and emitted energy. The spectral line shapes reflect the mixed character of the electronic states, intermediate between atomic and bandlike.
Reference:
Valence of YbS under pressure: A resonant inelastic x-ray emission study (Annese, E, Rueff, JP, Vanko, G, Grioni, M, Braicovich, L and Degiorgi, L, Gusmeroli, R and Dallera, C), In PHYSICAL REVIEW B, AMERICAN PHYSICAL SOC, volume 70, 2004.
Bibtex Entry:
@article{ ISI:000223716600042,
Author = {Annese, E and Rueff, JP and Vanko, G and Grioni, M and Braicovich, L and
   Degiorgi, L and Gusmeroli, R and Dallera, C},
Title = {{Valence of YbS under pressure: A resonant inelastic x-ray emission study}},
Journal = {{PHYSICAL REVIEW B}},
Year = {{2004}},
Volume = {{70}},
Number = {{7}},
Month = {{AUG}},
Abstract = {{We present spectroscopic data on the electronic structure of YbS under
   pressure. From resonant x-ray emission and x-ray absorption spectra in
   the high-resolution partial fluorescence yield mode, we find that the Yb
   valence increases from 2.3 at ambient pressure to 2.6 at 360 kbar. The
   accuracy of these estimates is enhanced by a combined analysis of
   emission spectra measured as a function of the incident and emitted
   energy. The spectral line shapes reflect the mixed character of the
   electronic states, intermediate between atomic and bandlike.}},
Publisher = {{AMERICAN PHYSICAL SOC}},
Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Annese, E (Corresponding Author), Univ Modena & Reggio Emilia, Dipartimento Fis, INFM, Via Campi 213-A, I-41100 Modena, Italy.
   Univ Modena & Reggio Emilia, Dipartimento Fis, INFM, I-41100 Modena, Italy.
   Univ Paris 06, Lab Chim Phys Mat & Rayonnement, UMR 7614, F-75231 Paris 05, France.
   European Synchrotron Radiat Facil, F-38043 Grenoble, France.
   Ecole Polytech Fed Lausanne, IPN, CH-1015 Lausanne, Switzerland.
   Politecn Milan, Dipartimento Fis, INFM, I-20133 Milan, Italy.
   ETH, Solid State Phys Lab, CH-8093 Zurich, Switzerland.
   Politecn Milan, Dipartimento Elettron & Informaz, I-20133 Milan, Italy.}},
DOI = {{10.1103/PhysRevB.70.075117}},
Article-Number = {{075117}},
ISSN = {{1098-0121}},
Keywords-Plus = {{RARE-EARTH MONOCHALCOGENIDES; TRANSITION}},
Research-Areas = {{Materials Science; Physics}},
Web-of-Science-Categories  = {{Materials Science, Multidisciplinary; Physics, Applied; Physics,
   Condensed Matter}},
ResearcherID-Numbers = {{Annese, Emilia/AAM-3070-2020
   Vanko, Gyorgy/B-8176-2012
   Rueff, Jean-Pascal/D-8938-2016
   }},
ORCID-Numbers = {{Vanko, Gyorgy/0000-0002-3095-6551
   Rueff, Jean-Pascal/0000-0003-3594-918X
   Annese, Emilia/0000-0002-4066-697X
   Braicovich, Lucio/0000-0001-6548-9140}},
Number-of-Cited-References = {{18}},
Times-Cited = {{15}},
Usage-Count-Last-180-days = {{0}},
Usage-Count-Since-2013 = {{7}},
Journal-ISO = {{Phys. Rev. B}},
Doc-Delivery-Number = {{851WG}},
Unique-ID = {{ISI:000223716600042}},
DA = {{2020-12-22}},
}

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