by Braicovich, L, Taguchi, M, Borgatti, F, Ghiringhelli, G and Tagliaferri, A, Brookes, NB, Uozumi, T and Kotani, A
Abstract:
We present experimental and theoretical results on CoO resonant Raman scattering (RRS) with excitation at many values in the whole Co2+-L-2,L-3, region, and with a final state containing a Co-3 s hole. The theory includes the final-state interaction between the configurations with one 3 s hole and that with two 3 p holes [configuration interaction (CI)]. A cluster calculation with CI reproduces the experimental results with excitation spanning the whole L-3 region. In the L-2 region the theory reproduces the evolution of the RRS doublet at higher outgoing energy. On this basis the role of CI and of the ligand hole effects are discussed vs the excitation energy. At lease 5 eV above the L-3 threshold, the experimental results show also a nondispersive component, with the intensity rapidly increasing with the excitation energy. The position and shape of this component are well reproduced by a model calculation accounting for all possible partitions between the transitions to the continuum and to the 3 d shell. However, the intensity of the calculated nondispersive component is about an order of magnitude smaller than the measured one. The implications of this fact in terms of the dynamics of the intermediate state are outlined.
Reference:
Resonant Raman scattering at the L thresholds with final 3s hole in 3d(2+) systems. II. The CoO case in the whole L-2,L-3 region (Braicovich, L, Taguchi, M, Borgatti, F, Ghiringhelli, G and Tagliaferri, A, Brookes, NB, Uozumi, T and Kotani, A), In PHYSICAL REVIEW B, AMER PHYSICAL SOC, volume 63, 2001.
Bibtex Entry:
@article{ ISI:000169531200028,
Author = {Braicovich, L and Taguchi, M and Borgatti, F and Ghiringhelli, G and
Tagliaferri, A and Brookes, NB and Uozumi, T and Kotani, A},
Title = {{Resonant Raman scattering at the L thresholds with final 3s hole in
3d(2+) systems. II. The CoO case in the whole L-2,L-3 region}},
Journal = {{PHYSICAL REVIEW B}},
Year = {{2001}},
Volume = {{63}},
Number = {{24}},
Month = {{JUN 15}},
Abstract = {{We present experimental and theoretical results on CoO resonant Raman
scattering (RRS) with excitation at many values in the whole
Co2+-L-2,L-3, region, and with a final state containing a Co-3 s hole.
The theory includes the final-state interaction between the
configurations with one 3 s hole and that with two 3 p holes
{[}configuration interaction (CI)]. A cluster calculation with CI
reproduces the experimental results with excitation spanning the whole
L-3 region. In the L-2 region the theory reproduces the evolution of the
RRS doublet at higher outgoing energy. On this basis the role of CI and
of the ligand hole effects are discussed vs the excitation energy. At
lease 5 eV above the L-3 threshold, the experimental results show also a
nondispersive component, with the intensity rapidly increasing with the
excitation energy. The position and shape of this component are well
reproduced by a model calculation accounting for all possible partitions
between the transitions to the continuum and to the 3 d shell. However,
the intensity of the calculated nondispersive component is about an
order of magnitude smaller than the measured one. The implications of
this fact in terms of the dynamics of the intermediate state are
outlined.}},
Publisher = {{AMER PHYSICAL SOC}},
Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Braicovich, L (Corresponding Author), INFM, Dipartimento Fis Politecn, PL da Vinci 32, I-20133 Milan, Italy.
INFM, Dipartimento Fis Politecn, I-20133 Milan, Italy.
Abdus Salam Int Ctr Theoret Phys, I-34100 Trieste, Italy.
Univ Modena, INFM, Dipartimento Fis, I-41100 Modena, Italy.
European Synchrotron Radiat Facil, F-38043 Grenoble, France.
Osaka Prefecture Univ, Coll Engn, Sakai, Osaka 5998531, Japan.
Univ Tokyo, Inst Solid State Phys, Chiba 2778581, Japan.}},
DOI = {{10.1103/PhysRevB.63.245115}},
Article-Number = {{245115}},
ISSN = {{2469-9950}},
EISSN = {{2469-9969}},
Keywords-Plus = {{FLUORESCENCE; SPECTROSCOPY}},
Research-Areas = {{Materials Science; Physics}},
Web-of-Science-Categories = {{Materials Science, Multidisciplinary; Physics, Applied; Physics,
Condensed Matter}},
ResearcherID-Numbers = {{Uozumi, Takayuki/AAB-6532-2020
Brookes, Nicholas B/C-6718-2019
Tagliaferri, Alberto/L-2903-2015
Ghiringhelli, Giacomo/D-1159-2014
Borgatti, Francesco/H-9777-2014
}},
ORCID-Numbers = {{Brookes, Nicholas B/0000-0002-1342-9530
Tagliaferri, Alberto/0000-0001-8001-1786
Ghiringhelli, Giacomo/0000-0003-0867-7748
Borgatti, Francesco/0000-0003-4659-4329
Braicovich, Lucio/0000-0001-6548-9140}},
Number-of-Cited-References = {{12}},
Times-Cited = {{13}},
Usage-Count-Last-180-days = {{0}},
Usage-Count-Since-2013 = {{5}},
Journal-ISO = {{Phys. Rev. B}},
Doc-Delivery-Number = {{446TX}},
Unique-ID = {{ISI:000169531200028}},
DA = {{2020-12-22}},
}
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