Resonant Raman scattering at the L thresholds with final 3s hole in 3d(2+) systems. I. Configuration interaction with two 3p hole final states in different systems

@article{ ISI:000169531200027,
Author = {Taguchi, M and Braicovich, L and Borgatti, F and Ghiringhelli, G and
   Tagliaferri, A and Brookes, NB and Uozumi, T and Kotani, A},
Title = {{Resonant Raman scattering at the L thresholds with final 3s hole in
   3d(2+) systems. I. Configuration interaction with two 3p hole final
   states in different systems}},
Journal = {{PHYSICAL REVIEW B}},
Year = {{2001}},
Volume = {{63}},
Number = {{24}},
Month = {{JUN 15}},
Abstract = {{The resonant Raman scattering (RRS) at the L edges with final 3 s hole
   is investigated in transition-metal oxides and oxidelike systems. Both
   theoretical and experimental work is presented showing that a
   satisfactory description can be obtained only by including the final
   stare configuration interaction (CI) between the configuration with a
   single 3 s hole interacting with the 3 d shell and the configuration
   with two 3 p holes. The effect is very well seen with L-2 excitation and
   is reflected in a strong decrease of the separation within the doublet
   seen in RRS with respect to the case without CI. We present calculations
   including CI on cluster and on ion with crystal held and new
   measurements on NiO, CoO, and MnFe2O4 with L-2 excitation; we also
   compare calculations with RRS measurements; on CaF2 taken from the
   Literature. We discuss the dependence on the atomic number and on the
   relevant parameters, by introducing a rationale explaining the nature of
   the coupling and the different behavior with n<5 and n<greater than or
   equal to>5, being n the 3 d occupation in the ground state. This
   assessment is of importance in future applications to detailed studies
   of strongly correlated systems.}},
Publisher = {{AMER PHYSICAL SOC}},
Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Ghiringhelli, G (Corresponding Author), Abdus Salam Int Ctr Theoret Phys, POB 586, I-34100 Trieste, Italy.
   Abdus Salam Int Ctr Theoret Phys, I-34100 Trieste, Italy.
   INFM, Dipartimento Fis Politecn, I-20133 Milan, Italy.
   Univ Modena, INFM, Dipartimento Fis, I-41100 Modena, Italy.
   European Synchrotron Radiat Facil, F-38043 Grenoble, France.
   Univ Osaka Prefecture, Coll Engn, Sakai, Osaka 5998531, Japan.
   Univ Tokyo, Inst Solid State Phys, Chiba 2778581, Japan.}},
DOI = {{10.1103/PhysRevB.63.245114}},
Article-Number = {{245114}},
ISSN = {{1098-0121}},
EISSN = {{1550-235X}},
Keywords-Plus = {{RAY EMISSION-SPECTROSCOPY; CORE-LEVEL; PHOTOEMISSION SPECTRA; ELECTRON
   CORRELATION; HELICAL UNDULATOR; METAL; CAF2; NIO; FLUORESCENCE;
   ABSORPTION}},
Research-Areas = {{Materials Science; Physics}},
Web-of-Science-Categories  = {{Materials Science, Multidisciplinary; Physics, Applied; Physics,
   Condensed Matter}},
ResearcherID-Numbers = {{Ghiringhelli, Giacomo/D-1159-2014
   Tagliaferri, Alberto/L-2903-2015
   Borgatti, Francesco/H-9777-2014
   Uozumi, Takayuki/AAB-6532-2020
   Brookes, Nicholas B/C-6718-2019
   }},
ORCID-Numbers = {{Ghiringhelli, Giacomo/0000-0003-0867-7748
   Tagliaferri, Alberto/0000-0001-8001-1786
   Borgatti, Francesco/0000-0003-4659-4329
   Brookes, Nicholas B/0000-0002-1342-9530
   Braicovich, Lucio/0000-0001-6548-9140}},
Number-of-Cited-References = {{26}},
Times-Cited = {{17}},
Usage-Count-Last-180-days = {{0}},
Usage-Count-Since-2013 = {{6}},
Journal-ISO = {{Phys. Rev. B}},
Doc-Delivery-Number = {{446TX}},
Unique-ID = {{ISI:000169531200027}},
DA = {{2020-12-22}},
}