by Chiuzbaian, S. G., Schmitt, T., Matsubara, M., Kotani, A. and Ghiringhelli, G., Dallera, C., Tagliaferri, A., Braicovich, L., Scagnoli, V., Brookes, N. B., Staub, U. and Patthey, L.
Abstract:
Resonant inelastic x-ray scattering (RIXS) measurements performed jointly across the M-2,M-3 and L-3 absorption thresholds are used to study CoO local electronic structure and are supported by model calculations. The high-resolution experimental data provide a precise set of parameters to describe the correlated response of valence electrons. The same core-hole independent set of parameters within the single impurity Anderson model is used to describe both the M (3p-3d) and L (2p-3d) resonances. This work shows that combining M and L scattering data provides an enhanced contrast view of the spectral weights. Measured M-2,M-3-RIXS spectra are observed to be free of charge-transfer or normal fluorescence contributions. Moreover the cross section of M-RIXS final states with change in spin multiplicity is low. Combining this information with L-edge studies establishes an appealing means of making a better separation between on-site and intersite (ligand to metal) electronic excitations. Experimental and theoretical features specific to RIXS studies performed at M and L edges are summarized as a basis for future studies on complex transition metal compounds.
Reference:
Combining M- and L-edge resonant inelastic x-ray scattering for studies of 3d transition metal compounds (Chiuzbaian, S. G., Schmitt, T., Matsubara, M., Kotani, A. and Ghiringhelli, G., Dallera, C., Tagliaferri, A., Braicovich, L., Scagnoli, V., Brookes, N. B., Staub, U. and Patthey, L.), In PHYSICAL REVIEW B, AMER PHYSICAL SOC, volume 78, 2008.
Bibtex Entry:
@article{ ISI:000262246400014,
Author = {Chiuzbaian, S. G. and Schmitt, T. and Matsubara, M. and Kotani, A. and
   Ghiringhelli, G. and Dallera, C. and Tagliaferri, A. and Braicovich, L.
   and Scagnoli, V. and Brookes, N. B. and Staub, U. and Patthey, L.},
Title = {{Combining M- and L-edge resonant inelastic x-ray scattering for studies
   of 3d transition metal compounds}},
Journal = {{PHYSICAL REVIEW B}},
Year = {{2008}},
Volume = {{78}},
Number = {{24}},
Month = {{DEC}},
Abstract = {{Resonant inelastic x-ray scattering (RIXS) measurements performed
   jointly across the M-2,M-3 and L-3 absorption thresholds are used to
   study CoO local electronic structure and are supported by model
   calculations. The high-resolution experimental data provide a precise
   set of parameters to describe the correlated response of valence
   electrons. The same core-hole independent set of parameters within the
   single impurity Anderson model is used to describe both the M (3p-3d)
   and L (2p-3d) resonances. This work shows that combining M and L
   scattering data provides an enhanced contrast view of the spectral
   weights. Measured M-2,M-3-RIXS spectra are observed to be free of
   charge-transfer or normal fluorescence contributions. Moreover the cross
   section of M-RIXS final states with change in spin multiplicity is low.
   Combining this information with L-edge studies establishes an appealing
   means of making a better separation between on-site and intersite
   (ligand to metal) electronic excitations. Experimental and theoretical
   features specific to RIXS studies performed at M and L edges are
   summarized as a basis for future studies on complex transition metal
   compounds.}},
Publisher = {{AMER PHYSICAL SOC}},
Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Chiuzbaian, SG (Corresponding Author), Univ Paris 06, UPMC, Lab Chim Phys Mat & Rayonnement, CNRS UMR 7614, F-75005 Paris, France.
   Chiuzbaian, S. G., Univ Paris 06, UPMC, Lab Chim Phys Mat & Rayonnement, CNRS UMR 7614, F-75005 Paris, France.
   Schmitt, T.; Staub, U.; Patthey, L., Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland.
   Matsubara, M., Univ Montpellier 2, Verres & Nanomat UMR 5587, Lab Colloides, F-34095 Montpellier 5, France.
   Kotani, A., RIKEN Spring8, Sayo, Hyogo 6795148, Japan.
   Kotani, A., High Energy Accelerator Res Org, IMSS, Photon Factory, Tsukuba, Ibaragi 3050801, Japan.
   Ghiringhelli, G., Politecn Milan, Dipartimento Fis, CNR INFM Coherentia, I-20133 Milan, Italy.
   Dallera, C., Politecn Milan, Dipartimento Fis, CNR INFM ULTRAS, I-20133 Milan, Italy.
   Tagliaferri, A.; Braicovich, L., Politecn Milan, Dipartimento Fis, CNR INFM SOFT, I-20133 Milan, Italy.
   Ghiringhelli, G., Politecn Milan, Dipartimento Fis, SOFT, I-20133 Milan, Italy.
   Scagnoli, V.; Brookes, N. B., European Synchrotron Radiat Facil, F-38043 Grenoble, France.}},
DOI = {{10.1103/PhysRevB.78.245102}},
Article-Number = {{245102}},
ISSN = {{2469-9950}},
EISSN = {{2469-9969}},
Keywords = {{Anderson model; band structure; cobalt compounds; X-ray scattering}},
Keywords-Plus = {{D-D EXCITATIONS; 2ND-HARMONIC GENERATION; EMISSION-SPECTROSCOPY;
   ABSORPTION-SPECTRA; COO; NIO; PHOTOEMISSION; COO(100); SOLIDS; WIDTHS}},
Research-Areas = {{Materials Science; Physics}},
Web-of-Science-Categories  = {{Materials Science, Multidisciplinary; Physics, Applied; Physics,
   Condensed Matter}},
Author-Email = {{gheorghe.chiuzbaian@upmc.fr}},
ResearcherID-Numbers = {{Ghiringhelli, Giacomo/D-1159-2014
   scagnoli, valerio/T-1355-2019
   Schmitt, Thorsten/A-7025-2010
   Staub, Urs/C-4914-2015
   Tagliaferri, Alberto/L-2903-2015
   scagnoli, valerio/C-6833-2008
   Patthey, Luc/G-6130-2018
   Matsubara, Masahiko/AAQ-3085-2020
   Brookes, Nicholas B/C-6718-2019
   }},
ORCID-Numbers = {{Ghiringhelli, Giacomo/0000-0003-0867-7748
   scagnoli, valerio/0000-0002-8116-8870
   Tagliaferri, Alberto/0000-0001-8001-1786
   scagnoli, valerio/0000-0002-8116-8870
   Patthey, Luc/0000-0001-6101-8069
   Matsubara, Masahiko/0000-0002-3608-6905
   Brookes, Nicholas B/0000-0002-1342-9530
   Staub, Urs/0000-0003-2035-3367
   Braicovich, Lucio/0000-0001-6548-9140}},
Number-of-Cited-References = {{35}},
Times-Cited = {{27}},
Usage-Count-Last-180-days = {{0}},
Usage-Count-Since-2013 = {{55}},
Journal-ISO = {{Phys. Rev. B}},
Doc-Delivery-Number = {{391PY}},
Unique-ID = {{ISI:000262246400014}},
OA = {{Green Published}},
DA = {{2020-12-22}},
}

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