by Chiuzbaian, S. G., Schmitt, T., Matsubara, M., Kotani, A. and Ghiringhelli, G., Dallera, C., Tagliaferri, A., Braicovich, L., Scagnoli, V., Brookes, N. B., Staub, U. and Patthey, L.
Abstract:
Resonant inelastic x-ray scattering (RIXS) measurements performed jointly across the M-2,M-3 and L-3 absorption thresholds are used to study CoO local electronic structure and are supported by model calculations. The high-resolution experimental data provide a precise set of parameters to describe the correlated response of valence electrons. The same core-hole independent set of parameters within the single impurity Anderson model is used to describe both the M (3p-3d) and L (2p-3d) resonances. This work shows that combining M and L scattering data provides an enhanced contrast view of the spectral weights. Measured M-2,M-3-RIXS spectra are observed to be free of charge-transfer or normal fluorescence contributions. Moreover the cross section of M-RIXS final states with change in spin multiplicity is low. Combining this information with L-edge studies establishes an appealing means of making a better separation between on-site and intersite (ligand to metal) electronic excitations. Experimental and theoretical features specific to RIXS studies performed at M and L edges are summarized as a basis for future studies on complex transition metal compounds.
Reference:
Combining M- and L-edge resonant inelastic x-ray scattering for studies of 3d transition metal compounds (Chiuzbaian, S. G., Schmitt, T., Matsubara, M., Kotani, A. and Ghiringhelli, G., Dallera, C., Tagliaferri, A., Braicovich, L., Scagnoli, V., Brookes, N. B., Staub, U. and Patthey, L.), In PHYSICAL REVIEW B, AMER PHYSICAL SOC, volume 78, 2008.
Bibtex Entry:
@article{ ISI:000262246400014,
Author = {Chiuzbaian, S. G. and Schmitt, T. and Matsubara, M. and Kotani, A. and
Ghiringhelli, G. and Dallera, C. and Tagliaferri, A. and Braicovich, L.
and Scagnoli, V. and Brookes, N. B. and Staub, U. and Patthey, L.},
Title = {{Combining M- and L-edge resonant inelastic x-ray scattering for studies
of 3d transition metal compounds}},
Journal = {{PHYSICAL REVIEW B}},
Year = {{2008}},
Volume = {{78}},
Number = {{24}},
Month = {{DEC}},
Abstract = {{Resonant inelastic x-ray scattering (RIXS) measurements performed
jointly across the M-2,M-3 and L-3 absorption thresholds are used to
study CoO local electronic structure and are supported by model
calculations. The high-resolution experimental data provide a precise
set of parameters to describe the correlated response of valence
electrons. The same core-hole independent set of parameters within the
single impurity Anderson model is used to describe both the M (3p-3d)
and L (2p-3d) resonances. This work shows that combining M and L
scattering data provides an enhanced contrast view of the spectral
weights. Measured M-2,M-3-RIXS spectra are observed to be free of
charge-transfer or normal fluorescence contributions. Moreover the cross
section of M-RIXS final states with change in spin multiplicity is low.
Combining this information with L-edge studies establishes an appealing
means of making a better separation between on-site and intersite
(ligand to metal) electronic excitations. Experimental and theoretical
features specific to RIXS studies performed at M and L edges are
summarized as a basis for future studies on complex transition metal
compounds.}},
Publisher = {{AMER PHYSICAL SOC}},
Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Chiuzbaian, SG (Corresponding Author), Univ Paris 06, UPMC, Lab Chim Phys Mat & Rayonnement, CNRS UMR 7614, F-75005 Paris, France.
Chiuzbaian, S. G., Univ Paris 06, UPMC, Lab Chim Phys Mat & Rayonnement, CNRS UMR 7614, F-75005 Paris, France.
Schmitt, T.; Staub, U.; Patthey, L., Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland.
Matsubara, M., Univ Montpellier 2, Verres & Nanomat UMR 5587, Lab Colloides, F-34095 Montpellier 5, France.
Kotani, A., RIKEN Spring8, Sayo, Hyogo 6795148, Japan.
Kotani, A., High Energy Accelerator Res Org, IMSS, Photon Factory, Tsukuba, Ibaragi 3050801, Japan.
Ghiringhelli, G., Politecn Milan, Dipartimento Fis, CNR INFM Coherentia, I-20133 Milan, Italy.
Dallera, C., Politecn Milan, Dipartimento Fis, CNR INFM ULTRAS, I-20133 Milan, Italy.
Tagliaferri, A.; Braicovich, L., Politecn Milan, Dipartimento Fis, CNR INFM SOFT, I-20133 Milan, Italy.
Ghiringhelli, G., Politecn Milan, Dipartimento Fis, SOFT, I-20133 Milan, Italy.
Scagnoli, V.; Brookes, N. B., European Synchrotron Radiat Facil, F-38043 Grenoble, France.}},
DOI = {{10.1103/PhysRevB.78.245102}},
Article-Number = {{245102}},
ISSN = {{2469-9950}},
EISSN = {{2469-9969}},
Keywords = {{Anderson model; band structure; cobalt compounds; X-ray scattering}},
Keywords-Plus = {{D-D EXCITATIONS; 2ND-HARMONIC GENERATION; EMISSION-SPECTROSCOPY;
ABSORPTION-SPECTRA; COO; NIO; PHOTOEMISSION; COO(100); SOLIDS; WIDTHS}},
Research-Areas = {{Materials Science; Physics}},
Web-of-Science-Categories = {{Materials Science, Multidisciplinary; Physics, Applied; Physics,
Condensed Matter}},
Author-Email = {{gheorghe.chiuzbaian@upmc.fr}},
ResearcherID-Numbers = {{Ghiringhelli, Giacomo/D-1159-2014
scagnoli, valerio/T-1355-2019
Schmitt, Thorsten/A-7025-2010
Staub, Urs/C-4914-2015
Tagliaferri, Alberto/L-2903-2015
scagnoli, valerio/C-6833-2008
Patthey, Luc/G-6130-2018
Matsubara, Masahiko/AAQ-3085-2020
Brookes, Nicholas B/C-6718-2019
}},
ORCID-Numbers = {{Ghiringhelli, Giacomo/0000-0003-0867-7748
scagnoli, valerio/0000-0002-8116-8870
Tagliaferri, Alberto/0000-0001-8001-1786
scagnoli, valerio/0000-0002-8116-8870
Patthey, Luc/0000-0001-6101-8069
Matsubara, Masahiko/0000-0002-3608-6905
Brookes, Nicholas B/0000-0002-1342-9530
Staub, Urs/0000-0003-2035-3367
Braicovich, Lucio/0000-0001-6548-9140}},
Number-of-Cited-References = {{35}},
Times-Cited = {{27}},
Usage-Count-Last-180-days = {{0}},
Usage-Count-Since-2013 = {{55}},
Journal-ISO = {{Phys. Rev. B}},
Doc-Delivery-Number = {{391PY}},
Unique-ID = {{ISI:000262246400014}},
OA = {{Green Published}},
DA = {{2020-12-22}},
}
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