by Chiuzbaian, S. G., Schmitt, T., Matsubara, M., Kotani, A. and Ghiringhelli, G., Dallera, C., Tagliaferri, A., Braicovich, L., Scagnoli, V., Brookes, N. B., Staub, U. and Patthey, L.
Abstract:
Resonant inelastic x-ray scattering (RIXS) measurements performed jointly across the M-2,M-3 and L-3 absorption thresholds are used to study CoO local electronic structure and are supported by model calculations. The high-resolution experimental data provide a precise set of parameters to describe the correlated response of valence electrons. The same core-hole independent set of parameters within the single impurity Anderson model is used to describe both the M (3p-3d) and L (2p-3d) resonances. This work shows that combining M and L scattering data provides an enhanced contrast view of the spectral weights. Measured M-2,M-3-RIXS spectra are observed to be free of charge-transfer or normal fluorescence contributions. Moreover the cross section of M-RIXS final states with change in spin multiplicity is low. Combining this information with L-edge studies establishes an appealing means of making a better separation between on-site and intersite (ligand to metal) electronic excitations. Experimental and theoretical features specific to RIXS studies performed at M and L edges are summarized as a basis for future studies on complex transition metal compounds.
Reference:
Combining M- and L-edge resonant inelastic x-ray scattering for studies of 3d transition metal compounds (Chiuzbaian, S. G., Schmitt, T., Matsubara, M., Kotani, A. and Ghiringhelli, G., Dallera, C., Tagliaferri, A., Braicovich, L., Scagnoli, V., Brookes, N. B., Staub, U. and Patthey, L.), In PHYSICAL REVIEW B, AMER PHYSICAL SOC, volume 78, 2008.
Bibtex Entry:
@article{ ISI:000262246400014, Author = {Chiuzbaian, S. G. and Schmitt, T. and Matsubara, M. and Kotani, A. and Ghiringhelli, G. and Dallera, C. and Tagliaferri, A. and Braicovich, L. and Scagnoli, V. and Brookes, N. B. and Staub, U. and Patthey, L.}, Title = {{Combining M- and L-edge resonant inelastic x-ray scattering for studies of 3d transition metal compounds}}, Journal = {{PHYSICAL REVIEW B}}, Year = {{2008}}, Volume = {{78}}, Number = {{24}}, Month = {{DEC}}, Abstract = {{Resonant inelastic x-ray scattering (RIXS) measurements performed jointly across the M-2,M-3 and L-3 absorption thresholds are used to study CoO local electronic structure and are supported by model calculations. The high-resolution experimental data provide a precise set of parameters to describe the correlated response of valence electrons. The same core-hole independent set of parameters within the single impurity Anderson model is used to describe both the M (3p-3d) and L (2p-3d) resonances. This work shows that combining M and L scattering data provides an enhanced contrast view of the spectral weights. Measured M-2,M-3-RIXS spectra are observed to be free of charge-transfer or normal fluorescence contributions. Moreover the cross section of M-RIXS final states with change in spin multiplicity is low. Combining this information with L-edge studies establishes an appealing means of making a better separation between on-site and intersite (ligand to metal) electronic excitations. Experimental and theoretical features specific to RIXS studies performed at M and L edges are summarized as a basis for future studies on complex transition metal compounds.}}, Publisher = {{AMER PHYSICAL SOC}}, Address = {{ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}}, Type = {{Article}}, Language = {{English}}, Affiliation = {{Chiuzbaian, SG (Corresponding Author), Univ Paris 06, UPMC, Lab Chim Phys Mat & Rayonnement, CNRS UMR 7614, F-75005 Paris, France. Chiuzbaian, S. G., Univ Paris 06, UPMC, Lab Chim Phys Mat & Rayonnement, CNRS UMR 7614, F-75005 Paris, France. Schmitt, T.; Staub, U.; Patthey, L., Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland. Matsubara, M., Univ Montpellier 2, Verres & Nanomat UMR 5587, Lab Colloides, F-34095 Montpellier 5, France. Kotani, A., RIKEN Spring8, Sayo, Hyogo 6795148, Japan. Kotani, A., High Energy Accelerator Res Org, IMSS, Photon Factory, Tsukuba, Ibaragi 3050801, Japan. Ghiringhelli, G., Politecn Milan, Dipartimento Fis, CNR INFM Coherentia, I-20133 Milan, Italy. Dallera, C., Politecn Milan, Dipartimento Fis, CNR INFM ULTRAS, I-20133 Milan, Italy. Tagliaferri, A.; Braicovich, L., Politecn Milan, Dipartimento Fis, CNR INFM SOFT, I-20133 Milan, Italy. Ghiringhelli, G., Politecn Milan, Dipartimento Fis, SOFT, I-20133 Milan, Italy. Scagnoli, V.; Brookes, N. B., European Synchrotron Radiat Facil, F-38043 Grenoble, France.}}, DOI = {{10.1103/PhysRevB.78.245102}}, Article-Number = {{245102}}, ISSN = {{2469-9950}}, EISSN = {{2469-9969}}, Keywords = {{Anderson model; band structure; cobalt compounds; X-ray scattering}}, Keywords-Plus = {{D-D EXCITATIONS; 2ND-HARMONIC GENERATION; EMISSION-SPECTROSCOPY; ABSORPTION-SPECTRA; COO; NIO; PHOTOEMISSION; COO(100); SOLIDS; WIDTHS}}, Research-Areas = {{Materials Science; Physics}}, Web-of-Science-Categories = {{Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter}}, Author-Email = {{gheorghe.chiuzbaian@upmc.fr}}, ResearcherID-Numbers = {{Ghiringhelli, Giacomo/D-1159-2014 scagnoli, valerio/T-1355-2019 Schmitt, Thorsten/A-7025-2010 Staub, Urs/C-4914-2015 Tagliaferri, Alberto/L-2903-2015 scagnoli, valerio/C-6833-2008 Patthey, Luc/G-6130-2018 Matsubara, Masahiko/AAQ-3085-2020 Brookes, Nicholas B/C-6718-2019 }}, ORCID-Numbers = {{Ghiringhelli, Giacomo/0000-0003-0867-7748 scagnoli, valerio/0000-0002-8116-8870 Tagliaferri, Alberto/0000-0001-8001-1786 scagnoli, valerio/0000-0002-8116-8870 Patthey, Luc/0000-0001-6101-8069 Matsubara, Masahiko/0000-0002-3608-6905 Brookes, Nicholas B/0000-0002-1342-9530 Staub, Urs/0000-0003-2035-3367 Braicovich, Lucio/0000-0001-6548-9140}}, Number-of-Cited-References = {{35}}, Times-Cited = {{27}}, Usage-Count-Last-180-days = {{0}}, Usage-Count-Since-2013 = {{55}}, Journal-ISO = {{Phys. Rev. B}}, Doc-Delivery-Number = {{391PY}}, Unique-ID = {{ISI:000262246400014}}, OA = {{Green Published}}, DA = {{2020-12-22}}, }
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