by Ruotsalainen, Kari O., Honkanen, Ari-Pekka, Collins, Stephen P., Monaco, Giulio, Sala, Marco Moretti, Krisch, Michael and Hamalainen, Keijo, Hakala, Mikko and Huotari, Simo
Abstract:
The Borrmann effect is the anomalous transmission of x-rays in perfect crystals under diffraction conditions. It arises from the interference of the incident and diffracted waves, which creates a standing wave with nodes at strongly absorbing atoms. Dipolar absorption of x-rays is thus diminished, which makes the crystal nearly transparent for certain x-ray wave vectors. Indeed, a relative enhancement of electric quadrupole absorption via the Borrmann effect has been demonstrated recently. Here we show that the Borrmann effect has a significantly larger impact on resonant x-ray emission than is observable in x-ray absorption. Emission from a dipole forbidden intermediate state may even dominate the corresponding x-ray spectra. Our work extends the domain of x-ray standing wave methods to resonant x-ray emission spectroscopy and provides means for novel spectroscopic experiments in d- and f-electron systems.
Reference:
Resonant X-ray emission with a standing wave excitation (Ruotsalainen, Kari O., Honkanen, Ari-Pekka, Collins, Stephen P., Monaco, Giulio, Sala, Marco Moretti, Krisch, Michael and Hamalainen, Keijo, Hakala, Mikko and Huotari, Simo), In SCIENTIFIC REPORTS, NATURE PUBLISHING GROUP, volume 6, 2016.
Bibtex Entry:
@article{ ISI:000371216100001,
Author = {Ruotsalainen, Kari O. and Honkanen, Ari-Pekka and Collins, Stephen P.
   and Monaco, Giulio and Sala, Marco Moretti and Krisch, Michael and
   Hamalainen, Keijo and Hakala, Mikko and Huotari, Simo},
Title = {{Resonant X-ray emission with a standing wave excitation}},
Journal = {{SCIENTIFIC REPORTS}},
Year = {{2016}},
Volume = {{6}},
Month = {{MAR 3}},
Abstract = {{The Borrmann effect is the anomalous transmission of x-rays in perfect
   crystals under diffraction conditions. It arises from the interference
   of the incident and diffracted waves, which creates a standing wave with
   nodes at strongly absorbing atoms. Dipolar absorption of x-rays is thus
   diminished, which makes the crystal nearly transparent for certain x-ray
   wave vectors. Indeed, a relative enhancement of electric quadrupole
   absorption via the Borrmann effect has been demonstrated recently. Here
   we show that the Borrmann effect has a significantly larger impact on
   resonant x-ray emission than is observable in x-ray absorption. Emission
   from a dipole forbidden intermediate state may even dominate the
   corresponding x-ray spectra. Our work extends the domain of x-ray
   standing wave methods to resonant x-ray emission spectroscopy and
   provides means for novel spectroscopic experiments in d- and f-electron
   systems.}},
Publisher = {{NATURE PUBLISHING GROUP}},
Address = {{MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Ruotsalainen, KO (Corresponding Author), Univ Helsinki, Dept Phys, POB 64, FI-00014 Helsinki, Finland.
   Ruotsalainen, Kari O.; Honkanen, Ari-Pekka; Hamalainen, Keijo; Hakala, Mikko; Huotari, Simo, Univ Helsinki, Dept Phys, POB 64, FI-00014 Helsinki, Finland.
   Collins, Stephen P., Diamond Light Source, Didcot OX11 0DE, Oxon, England.
   Monaco, Giulio, Univ Trento, Dept Phys, Via Sommar 14, I-38123 Povo, TN, Italy.
   Sala, Marco Moretti; Krisch, Michael, ESRF, CS40220, F-38043 Grenoble 9, France.}},
DOI = {{10.1038/srep22648}},
Article-Number = {{22648}},
ISSN = {{2045-2322}},
Keywords-Plus = {{DYNAMICAL DIFFRACTION; CIRCULAR-DICHROISM; ABSORPTION SPECTROSCOPY;
   FLUORESCENCE SCATTERING; L(III) EDGE; TRANSITIONS; GADOLINIUM; CRYSTALS;
   SPECTRA; PROBE}},
Research-Areas = {{Science & Technology - Other Topics}},
Web-of-Science-Categories  = {{Multidisciplinary Sciences}},
Author-Email = {{kari.ruotsalainen@helsinki.fi}},
ResearcherID-Numbers = {{Hamalainen, Keijo J/A-3986-2010
   Moretti, Marco/AAF-9255-2019
   Collins, Stephen/AAG-7910-2020
   Monaco, Giulio/AAW-4387-2020
   Sala, Marco Moretti/H-1034-2014
   Krisch, Michael H/U-5662-2018
   }},
ORCID-Numbers = {{Hamalainen, Keijo J/0000-0002-9234-9810
   Moretti, Marco/0000-0002-9744-9976
   Monaco, Giulio/0000-0003-2497-6422
   Sala, Marco Moretti/0000-0002-9744-9976
   Krisch, Michael H/0000-0001-7423-1715
   Hakala, Mikko/0000-0003-2829-4736
   Huotari, Simo/0000-0003-4506-8722
   Honkanen, Ari-Pekka/0000-0002-6822-3062}},
Funding-Acknowledgement = {{Academy of FinlandAcademy of Finland {[}1254065, 1283136, 1259526,
   1260204, 1259599]}},
Funding-Text = {{We acknowledge the European Synchrotron Radiation Facility for beamtime.
   This work was supported by Academy of Finland projects 1254065, 1283136,
   1259526, 1260204 and 1259599.}},
Number-of-Cited-References = {{24}},
Times-Cited = {{2}},
Usage-Count-Last-180-days = {{0}},
Usage-Count-Since-2013 = {{14}},
Journal-ISO = {{Sci Rep}},
Doc-Delivery-Number = {{DF3AM}},
Unique-ID = {{ISI:000371216100001}},
OA = {{DOAJ Gold, Green Published}},
DA = {{2020-12-22}},
}

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