{"id":2213,"date":"2021-01-26T10:11:50","date_gmt":"2021-01-26T10:11:50","guid":{"rendered":"https:\/\/www.polimix.fisi.polimi.it\/?p=2213"},"modified":"2021-01-29T08:53:56","modified_gmt":"2021-01-29T08:53:56","slug":"crystalline-and-magnetic-structure-of-ba2cuo3%ce%b4-investigated-by-x-ray-absorption-spectroscopy-and-resonant-inelastic-x-ray-scattering","status":"publish","type":"post","link":"https:\/\/www.polimix.fisi.polimi.it\/?p=2213","title":{"rendered":"Crystalline and magnetic structure of Ba2CuO3+\u03b4 investigated by x-ray absorption spectroscopy and resonant inelastic x-ray scattering"},"content":{"rendered":"\t\t
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Crystalline and magnetic structure of Ba2CuO3+\u03b4 investigated by x-ray absorption spectroscopy and resonant inelastic x-ray scattering<\/span><\/a><\/p>\n

Motivated by the recent synthesis of Ba2CuO3+\u03b4 (BCO), a high temperature superconducting cuprate with putative d3z2\u2212r2 ground state symmetry, we investigated its electronic structure by means of Cu L3 x-ray absorption (XAS) and resonant inelastic x-ray scattering (RIXS) at the Cu L3 edge on a poly-crystalline sample. We show that the XAS profile of BCO is characterised by two peaks associated to inequivalent Cu sites, and that its RIXS response features a single, sharp peak associated to crystal-field excitations. We argue that these observations are only partially compatible with the previously proposed crystal structure of BCO. Based on our spectroscopic results and on previously published powder diffraction measurements, we propose a crystalline structure characterized by two inequivalent Cu sites located at alternated planes along the caxis: nominally trivalent Cu(1) belonging to very short Cu-O chains, and divalent Cu(2) in the oxygen deficient CuO1.5 planes. We also analyze the low-energy region of the RIXS spectra to estimate the magnitude of the magnetic interactions in BCO and find that in-plane nearest neighbor superexchange exceeds 120 meV, similarly to that of other layered cuprates. Although these results do not support the pure d3z2\u2212r2 ground state scenario, they hint at a significant departure from the common quasi-2D electronic structure of super-conducting cuprates of pure dx2\u2212y2 symmetry.<\/p>\n

Physica C: Superconductivity and its applications 581, 1353810 (2021)<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t

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Crystalline and magnetic structure of Ba2CuO3+\u03b4 investigated by x-ray absorption spectroscopy and resonant inelastic x-ray scattering Motivated by the recent synthesis of Ba2CuO3+\u03b4 (BCO), a high temperature superconducting cuprate with putative d3z2\u2212r2 ground state symmetry, we investigated its electronic structure by means of Cu L3 x-ray absorption (XAS) and resonant inelastic x-ray scattering (RIXS) at the […]<\/p>\n","protected":false},"author":8,"featured_media":2228,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[7],"tags":[],"class_list":["post-2213","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-publications"],"_links":{"self":[{"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=\/wp\/v2\/posts\/2213","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2213"}],"version-history":[{"count":12,"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=\/wp\/v2\/posts\/2213\/revisions"}],"predecessor-version":[{"id":2408,"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=\/wp\/v2\/posts\/2213\/revisions\/2408"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=\/wp\/v2\/media\/2228"}],"wp:attachment":[{"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2213"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2213"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.polimix.fisi.polimi.it\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2213"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}